NITROXIDE COMPLEXES WITH THE SOLID LEWIS-ACIDS

被引：30
作者：
LUNINA, EV
MARKARYAN, GL
PARENAGO, OO
FIONOV, AV
机构：
[1] Department of Chemistry, Moscow State University, Lenin Hills
来源：
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS | 1993年 / 72卷
关键词：
ALUMINA; ESR; LEWIS ACID SITES; NITROXIDE; PARAMAGNETIC PROBE; ZEOLITE;
D O I：
10.1016/0927-7757(93)80483-U
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The possibilities of the paramagnetic probe method for investigating Lewis acid sites (LASs) on the surfaces of oxide catalysts (Al2O3, Al2O3-SiO2, zeolites etc.) are discussed. Nitroxides of different structures were used as paramagnetic probes. The experimental and calculated results have clarified the structure of nitroxide complexes with LASs and have led to an assessment of the impact of steric hindrance on the orientation and mobility of complex-bonded radicals. It has been demonstrated that the method is highly advantageous for the quantitative and qualitative control of surface acidity.
引用
收藏
页码：333 / 343
页数：11
相关论文
共 50 条
[31]   The development and applications of CAVERN methods for in situ NMR studies of reactions on solid acids [J].
T. Xu ;
J.F. Haw .
Topics in Catalysis, 1997, 4 :109-118
[32]   Catalysis on solid acids: Mechanism and catalyst descriptors in oligomerization reactions of light alkenes [J].
Sarazen, Michele L. ;
Doskocil, Eric ;
Iglesia, Enrique .
JOURNAL OF CATALYSIS, 2016, 344 :553-569
[33]   The Solid Acid Catalyzed Esterification of Free Fatty Acids in Pongamia Pinnata Oil [J].
Thiruvengadaravi, K. V. ;
Nanadagopal, J. ;
Bala, V. Sathya Selva ;
Kirupha, S. Dinesh ;
Vijayalakshmi, P. ;
Sivanesan, S. .
ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS, 2012, 34 (21) :2016-2022
[34]   Nitroxide spin probe study of probe size, hydrogen bonding and polymer matrix rigidity effects on poly(acrylic acid)/poly(ethylene oxide) complexes [J].
Tan, L ;
Chen, SM ;
Ping, ZH ;
Shen, YM .
MAGNETIC RESONANCE IN CHEMISTRY, 2003, 41 (07) :481-488
[35]   Synthesis, crystal structures, and magnetic properties of cobalt(II)-hexafluoro-acetylacetonate complexes with two new triazole-substituted nitronyl and imino nitroxide [J].
J. Chen ;
Y. J. Zhang ;
J. J. Wang ;
Q. Huang .
Russian Journal of Coordination Chemistry, 2014, 40 :143-148
[36]   The Heterogenized Hexazatricyclic Complexes as Solid Acid Catalyst for the Degradation of Rhodamine-b [J].
Gontu, Ramanjaneya Reddy ;
Kattela, Chennakesavulu ;
Sengottuvelan, Balasubramanian .
CHEMISTRYSELECT, 2020, 5 (32) :10048-10054
[37]   Theoretical Study of the Regioselectivity of the Interaction of 3-Methyl-4-pyrimidone and 1-Methyl-2-pyrimidone with Lewis Acids [J].
Kasende, Okuma Emile ;
Muya, Jules Tshishimbi ;
Broeckaert, Lies ;
Maes, Guido ;
Geerlings, Paul .
JOURNAL OF PHYSICAL CHEMISTRY A, 2012, 116 (33) :8608-8614
[38]   Bifunctional Solid Lewis Acid-Base Catalysts for Efficient Conversion of the Glucose-Xylose Mixture to Methyl Lactate [J].
Qu, Hongjin ;
Chen, Xu ;
Liu, Zhongyi ;
Yang, Xiaomei ;
Zhou, Lipeng .
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2023, 11 (06) :2387-2396
[39]   Compensation between activation entropy and enthalpy in reactions of aromatic hydrocarbons catalyzed by solid acids [J].
Nakamura, Koshiro ;
Mizuta, Ryo ;
Suganuma, Satoshi ;
Tsuji, Etsushi ;
Katada, Naonobu .
CATALYSIS COMMUNICATIONS, 2017, 102 :103-107
[40]   Exceptionally high yields of furfural from assorted raw biomass over solid acids [J].
Bhaumik, Prasenjit ;
Dhepe, Paresh Laxmikant .
RSC ADVANCES, 2014, 4 (50) :26215-26221
12345