NITROXIDE COMPLEXES WITH THE SOLID LEWIS-ACIDS

被引：30
作者：
LUNINA, EV
MARKARYAN, GL
PARENAGO, OO
FIONOV, AV
机构：
[1] Department of Chemistry, Moscow State University, Lenin Hills
来源：
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS | 1993年 / 72卷
关键词：
ALUMINA; ESR; LEWIS ACID SITES; NITROXIDE; PARAMAGNETIC PROBE; ZEOLITE;
D O I：
10.1016/0927-7757(93)80483-U
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The possibilities of the paramagnetic probe method for investigating Lewis acid sites (LASs) on the surfaces of oxide catalysts (Al2O3, Al2O3-SiO2, zeolites etc.) are discussed. Nitroxides of different structures were used as paramagnetic probes. The experimental and calculated results have clarified the structure of nitroxide complexes with LASs and have led to an assessment of the impact of steric hindrance on the orientation and mobility of complex-bonded radicals. It has been demonstrated that the method is highly advantageous for the quantitative and qualitative control of surface acidity.
引用
收藏
页码：333 / 343
页数：11
相关论文
共 50 条
[21]   Alumina Graphene Catalytic Condenser for Programmable Solid Acids [J].
Onn, Tzia Ming ;
Gathmann, Sallye R. ;
Wang, Yuxin ;
Patel, Roshan ;
Guo, Silu ;
Chen, Han ;
Soeherman, Jimmy K. ;
Christopher, Phillip ;
Rojas, Geoffrey ;
Mkhoyan, K. Andre ;
Neurock, Matthew ;
Abdelrahman, Omar A. ;
Frisbie, C. Daniel ;
Dauenhauer, Paul J. .
JACS AU, 2022, 2 (05) :1123-1133
[22]   Mechanisms of Double-Bond Isomerization Reactions of n-Butene on Different Lewis Acids [J].
Yi, Fengjiao ;
He, Peng ;
Chen, Huimin ;
He, Yurong ;
Tao, Zhichao ;
Li, Tao ;
Zhao, Guoyan ;
Yun, Yifeng ;
Wen, Xiaodong ;
Yang, Yong ;
Li, Yongwang .
ACS CATALYSIS, 2021, 11 (17) :11293-11304
[23]   Synergistic catalysis strategy of Lewis and Brønsted acids for superior aromatic production in biomass pyrolysis [J].
Xia, Shengpeng ;
Ou, Jionghua ;
Liang, Junming ;
Chen, Shu ;
Wang, Zhihao ;
Zhao, Zengli ;
Zhao, Kun ;
Zheng, Anqing .
INDUSTRIAL CROPS AND PRODUCTS, 2025, 226
[24]   Two hetero-spin metal–radical complexes exhibiting strong antiferromagnetic interactions between the metal ions and nitroxide radicals [J].
Dong-Zhao Gao ;
Dai-Zheng Liao ;
Zong-Hui Jiang ;
Shi-Ping Yan .
Transition Metal Chemistry, 2008, 33 :107-112
[25]   Expanding the Diversity of Nitroxide-Based Paramagnetic Probes Conjugated to Non-Canonical Amino Acids for Sdsl-Epr Applications [J].
Bizet, Maxime ;
Balazsi, Aron ;
Biaso, Frederic ;
Byrne, Deborah ;
Etienne, Emilien ;
Guigliarelli, Bruno ;
Urban, Philippe ;
Dorlet, Pierre ;
Truan, Gilles ;
Gerbaud, Guillaume ;
Kalai, Tamas ;
Martinho, Marlene .
CHEMBIOCHEM, 2025, 26 (07)
[26]   Environmentally Benign Contemporary Friedel-Crafts Chemistry by Solid Acids [J].
Dasgupta, Sujaya ;
Torok, Bela .
CURRENT ORGANIC SYNTHESIS, 2008, 5 (04) :321-342
[27]   Beyond ketonization: selective conversion of carboxylic acids to olefins over balanced Lewis acid-base pairs [J].
Baylon, Rebecca A. L. ;
Sun, Junming ;
Martin, Kevin J. ;
Venkitasubramanian, Padmesh ;
Wang, Yong .
CHEMICAL COMMUNICATIONS, 2016, 52 (28) :4975-4978
[28]   Syntheses, crystal structures, and magnetic properties of three one-dimensional metal–nitroxide complexes linked by 1,4-cyclohexanedicarboxylate ligands [J].
Hong-Dao Li ;
Yi-Wen Chen ;
Dong-Zhao Gao ;
Xiu-Guang Wang ;
Zhong-Yi Liu ;
Ya-Qiu Sun ;
Guo-Ying Zhang ;
Yan-Yan Xu .
Transition Metal Chemistry, 2014, 39 :225-232
[29]   Preparation and structural studies of organotin(IV) complexes formed with organic carboxylic acids [J].
Byung-Seon Choi ;
Geun-Il Park ;
Jung-Won Lee ;
Ho-Yeon Yang ;
Seung-Kon Ryu .
Journal of Radioanalytical and Nuclear Chemistry, 2003, 256 (1) :19-26
[30]   Syntheses, crystal structures, and magnetic properties of two monometallic tri-spin complexes involving nitronyl nitroxide radicals-lanthanide ions [J].
R. N. Liu ;
S. P. Zhao ;
C. X. Xiong .
Russian Journal of Coordination Chemistry, 2013, 39 :808-812
12345