MATHEMATICAL-DESCRIPTION OF DIFFERENTIAL SCANNING CALORIMETRY BASED ON PERIODIC TEMPERATURE MODULATION

被引：408

作者：

WUNDERLICH, B ^{[1
]}

JIN, YM ^{[1
]}

BOLLER, A ^{[1
]}

机构：

[1] OAK RIDGE NATL LAB,DIV CHEM,OAK RIDGE,TN 37831

来源：

THERMOCHIMICA ACTA | 1994年 / 238卷

关键词：

D O I：

10.1016/S0040-6031(94)85214-6

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The changes needed in the mathematical description of differential scanning calorimetry caused by periodical modulation of temperature are presented. Calibration procedures and possible extensions of the method are suggested, all based on the model of scanning calorimetry without temperature gradient within the sample. The basic differential equation for heat flow under modulation conditions is solved and the steady state identified. The main advantage of modulated differential thermal analysis is the elimination of nonperiodic heat losses and gains. It is suggested that the precision of heat capacity measurement may be increased by a factor of 10 using proper calibration. The thermal analysis in transition regions is discussed.

引用

页码：277 / 293

页数：17

共 26 条

[1]

BOLLER A, UNPUB

[2] ANALYSIS OF THE CONTRIBUTION OF SKELETAL VIBRATIONS TO THE HEAT-CAPACITY OF LINEAR MACROMOLECULES IN THE SOLID-STATE [J].

CHEBAN, YV ;

LAU, SF ;

WUNDERLICH, B .

COLLOID AND POLYMER SCIENCE, 1982, 260 (01) :9-19

[3]

EYRING H, 1936, CHEM PHYS, V4, P238

[4]

Frenkel Y. I., 1946, KINETIC THEORY LIQUI

[5] MODULATED DIFFERENTIAL SCANNING CALORIMETRY [J].

GILL, PS ;

SAUERBRUNN, SR ;

READING, M .

JOURNAL OF THERMAL ANALYSIS, 1993, 40 (03) :931-939

[6]

HEMMINGER WF, 1984, CALORIMETRY

[7] BULK VISCOSITY OF POLYMERIC SYSTEMS [J].

HIRAI, N ;

EYRING, H .

JOURNAL OF POLYMER SCIENCE, 1959, 37 (131) :51-70

[8] BULK VISCOSITY OF LIQUIDS [J].

HIRAI, N ;

EYRING, H .

JOURNAL OF APPLIED PHYSICS, 1958, 29 (05) :810-816

[9] SINGLE RUN HEAT-CAPACITY MEASUREMENTS .3. DATA-ANALYSIS [J].

JIN, Y ;

WUNDERLICH, B .

JOURNAL OF THERMAL ANALYSIS, 1992, 38 (10) :2257-2272

[10] SINGLE RUN HEAT-CAPACITY MEASUREMENTS .2. EXPERIMENTS AT SUBAMBIENT TEMPERATURE [J].

JIN, Y ;

WUNDERLICH, B .

JOURNAL OF THERMAL ANALYSIS, 1990, 36 (04) :1519-1543

← 1 2 3 →