SYNTHESIS, CHARACTERIZATION AND ELECTRICAL-PROPERTIES OF PHTHALOCYANINES SUBSTITUTED WITH 17-MEMBERED TRIOXADIAZA MACROCYCLES

被引：86

作者：

GUMUS, G

OZTURK, ZZ

AHSEN, V

GUL, A

BEKAROGLU, O

机构：

[1] TUBITAK,MARMARA RES CTR,DEPT ELECTR & SEMICOND TECHNOL,GEBZE 41470,TURKEY

[2] TECH UNIV ISTANBUL,DEPT CHEM,ISTANBUL,TURKEY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1992年 / 16期

关键词：

D O I：

10.1039/dt9920002485

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New phthalocyanines (M = Cu, Zn, Ni, Co or 2H) substituted with four 17-membered trioxadiaza macrocycles have been prepared. Detosylation of aza groups with concentrated sulfuric acid simultaneously leads to sulfonated groups on the aromatic rings of the macrocyclic substituents. While the N-tosylated derivatives are soluble in organic solvents, the detosylated ones are extremely soluble in water. The electrical conductivities of the phthalocyanines measured as gold sandwiches are about 10(-12) S m-1 in vacuo and show some increase in the presence of dry air.

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页码：2485 / 2489

页数：5

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