A NEW VERSION OF THE REACTIVE INFINITE-ORDER SUDDEN APPROXIMATION - THE INCORPORATION OF OPTICAL POTENTIALS

被引:20
作者
BAER, M
NG, CY
NEUHAUSER, D
机构
[1] US DOE,AMES LAB,AMES,IA 50011
[2] IOWA STATE UNIV SCI & TECHNOL,DEPT CHEM,AMES,IA 50011
[3] PRINCETON UNIV,DEPT CHEM,PRINCETON,NJ 08544
关键词
D O I
10.1016/0009-2614(90)85643-Q
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this work the ordinary inelastic infinite-order sudden approximation was coupled with optical potentials to formulate a new version for the reactive infinite-order sudden approximation (RIOSA). Cross sections obtained for the exothermic reactions Ar+H2+ (ν+=0, 1)→ArH++H were found to be similar to both the experimental and the quasiclassical cross sections but two to three times larger than those obtained with the previous RIOSA version. © 1990.
引用
收藏
页码:534 / 540
页数:7
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