THE 1ST STRUCTURE OF A SELENANE - METAL(II) COMPLEXES WITH THE 2,4,6-TRIS(TRIFLUOROMETHYL)-SELENOPHENOLATO LIGAND

被引：39
作者：
LABAHN, D [1 ]
BOHNEN, FM [1 ]
HERBSTIRMER, R [1 ]
POHL, E [1 ]
STALKE, D [1 ]
ROESKY, HW [1 ]
机构：
[1] UNIV GOTTINGEN,INST ANORGAN CHEM,TAMMANNSTR 4,D-37077 GOTTINGEN,GERMANY
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1994年 / 620卷 / 01期
关键词：
SELENANE; BIS(SELENOPHENOLATO)METAL COMPLEXES; CRYSTAL STRUCTURES;
D O I：
10.1002/zaac.19946200107
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
R(f)SeH 1 is obtained in a single pot reaction of R(f)Li [R(f) = 2,4,6-tris(trifluoromethyl)phenyl] with elemental seleniun and following treatment with HBF4. 1 gave the first crystal structure of a selenane. Reaction of 1 with M[N(SiMe3)2]2 (M = Zn, Pb) in the molar ratio of 2:1 yielded the metal selenophenolates Zn(SeR(f))2 . HN(SiMe3)2 2 and [Pb(SeRf)2]2 3. 2 crystallizes as hexamethyldisilazane adduct, 3 as a dimer.
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页码：41 / 47
页数：7
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