ORIENTATION OF BENZENE AND PYRIDINE ON ZNO(10(1)OVER-BAR0)

被引：21
作者：
WALSH, JF
DAVIS, R
MURYN, CA
THORNTON, G
DHANAK, VR
PRINCE, KC
机构：
[1] UNIV MANCHESTER, DEPT CHEM, MANCHESTER M13 9PL, LANCS, ENGLAND
[2] SINCROTRONE TRIESTE, I-34012 TRIESTE, ITALY
来源：
PHYSICAL REVIEW B | 1993年 / 48卷 / 19期
关键词：
D O I：
10.1103/PhysRevB.48.14749
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
High-resolution, polarization-dependent C K-edge near-edge x-ray absorption fine structure spectra of benzene and pyridine on ZnO(1010BAR) indicate that both species are oriented by the substrate. At 180 K benzene lies flat on the surface to within 10-degrees, while at 295 K pyridine adopts an upright geometry with the ring close to parallel to the (1120BAR) plane. These geometries are similar to those found on metal surfaces.
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收藏
页码：14749 / 14752
页数：4
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