1-[(4-Bromophenyl)(morpholin-4-yl)-methyl]naphthalen-2-ol

被引:0
|
作者
Zhao, Qun [1 ]
机构
[1] Nanjing Univ Chinese Med, Sch Pharmaceut Sci, Nanjing 210046, Jiangsu, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷
关键词
data-to-parameter ratio = 14.6; mean σ(C-C) = 0.012 Å; R factor = 0.083; single-crystal X-ray study; T = 293 K; wR factor = 0.192;
D O I
10.1107/S160053681200459X
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compound, C 21H 20BrNO 2, was obtained via a one-pot synthesis from the reaction of 4-bromo-benzaldehyde, 2-naphthol and morpholine. In the asymmetric unit, there are four mol-ecules with similar structures. The morpholine ring adopts a chair conformation, and the hy-droxy group links with the morpholine via an intra-molecular O - H⋯N hydrogen bond. The bromo-phenyl ring is approximately perpendicular to the mean pane of the naphthalene system at dihedral angles of 76.7 (3), 81.4 (3), 79.7 (3) and 84.5 (3)° in the four independent mol-ecules. Weak C - H⋯O hydrogen bonds are observed in the crystal.
引用
收藏
页码:O812 / U2775
页数:16
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