PHOSPHASILENE SYNTHESIS AND REACTIVITY - AN IMPROVED ROUTE TO 1-(2,4,6-TRI-TERT-BUTYLPHENYL)-2-TERT-BUTYL-2-(2,4,6-TRI-ISOPROPYLPHENYL)PHOSPHASILENE

被引：69
|
作者：
VANDENWINKEL, Y
BASTIAANS, HMM
BICKELHAUPT, F
机构：
[1] Scheikundig Laboratorium, Vrije Universiteit, 1081 HV Amsterdam
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 405卷 / 02期
关键词：
D O I：
10.1016/0022-328X(91)86271-Q
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new route was developed for the synthesis of a specific phosphasilene, 1-(2,4,6-tri-tert-butylphenyl)-2-tert-butyl-2-(2,4,6-tri-isopropylphenyl)phosphasilene (1e). Several novel phosphasilenes (1) with various substituents on phosphorus have been synthesized. The influence of the substituents on the phosphorus and silicon chemical shifts and the stability of the phosphasilenes is analyzed. The chemical reactivity of 1e has been investigated.
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收藏
页码：183 / 194
页数：12
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