STRUCTURE OF D-THREO-2,5-HEXODIULOSONIC ACID AND DERIVATIVES IN SOLUTION

被引:13
作者
ANDREWS, GC [1 ]
BACON, BE [1 ]
BORDNER, J [1 ]
HENNESSEE, GLA [1 ]
机构
[1] N CAROLINA STATE UNIV, RALEIGH, NC 27607 USA
关键词
D O I
10.1016/S0008-6215(00)83790-8
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
The structure of d-threo-2,5-hexodiulosonic acid (1) and various derivatives in solution was determined by 13C-n.m.r. spectroscopy to be a hydrated, pyranose form. The structures of the methyl ester of 1 and of its 5-(dimethyl acetal) were confirmed by chemical means and by X-ray structure analysis. © 1979.
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页码:25 / 36
页数:12
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