SYNTHESIS OF RUTHENIUM RHODIUM HETEROBIMETALLIC COMPLEXES VIA RING-OPENING REACTIONS OF BIDENTATE PHOSPHINE-LIGANDS - CRYSTAL-STRUCTURES OF [RU(C5H5)CL(PH2PC(=CH2)PPH2)] AND [(C5H5)RU(MU-CO)2(MU-PH2PC(=CH2)PPH2)RHCL2]

被引：15

作者：

BROWN, MP ^{[1
]}

BURNS, D ^{[1
]}

DAS, R ^{[1
]}

DOLBY, PA ^{[1
]}

HARDING, MM ^{[1
]}

JONES, RW ^{[1
]}

ROBINSON, EJ ^{[1
]}

SMITH, AK ^{[1
]}

机构：

[1] UNIV LIVERPOOL,DEPT CHEM,LIVERPOOL L69 3BX,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1991年 / 03期

关键词：

D O I：

10.1039/dt9910000351

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of [Ru(C5H5)Cl(dppen)] 1 [dppen = 1,1-bis(diphenylphosphino)ethene] and [Ru(C5H5)-Cl(dppm)] 2 [dppm = bis(diphenylphosphino)methane] with [{RhCl(CO)2{2] leads to the immediate formation of the heterobimetallic complexes [(C5H5)Ru(mu-CO)2(mu-L2)RhCl2] (L2 = dppen 3 or dppm 4) in high yield. The structures of complexes 1 and 3 have been determined by X-ray diffraction.

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页码：351 / 354

页数：4

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