MICROEMULSION POLYMERIZATION OF VINYL-ACETATE

被引：16

作者：

DONESCU, D ^{[1
]}

ANGHEL, D ^{[1
]}

GOSA, K ^{[1
]}

BALCAN, M ^{[1
]}

机构：

[1] ICECHIM,CTR PHYS CHEM,R-77208 BUCHAREST,ROMANIA

来源：

ANGEWANDTE MAKROMOLEKULARE CHEMIE | 1991年 / 188卷

关键词：

D O I：

10.1002/apmc.1991.051880101

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Vinyl acetate (VAc) was polymerized with ammonium persulfate in microemulsions prepared from VAc, sodium dodecyl sulfate, n-propanol and water. The polymerization rates were smaller than those in emulsion. The reaction orders versus the initiator and tenside concentration were 0.9 and -0.5, respectively. The polymerization rate and molecular weights decreased by increasing the surfactant and the cosurfactant concentrations. By cooling the finally obtained microemulsions, a polymer solution coacervation took place.

引用

页码：1 / 10

页数：10

共 48 条

[1]

ANGHEL DF, 1988, COLLOID POLYM SCI, V77, P127

[2] POLYMERIZED MICRO-EMULSIONS [J].