INTRODUCING TPPTS AND RELATED LIGANDS FOR INDUSTRIAL BIPHASIC PROCESSES

被引：294
作者：
CORNILS, B [1 ]
KUNTZ, EG [1 ]
机构：
[1] CPE,ELECTROCHIM LAB,F-69622 VILLEURBANNE,FRANCE
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 502卷 / 1-2期
关键词：
HOMOGENEOUS CATALYSIS; AQUEOUS CATALYST; IMMOBILIZATION;
D O I：
10.1016/0022-328X(95)05820-F
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
This paper describes the beginnings and development of biphasic homogeneous catalysis. With water-soluble triphenylphosphine trisulfonate as the ligand, Rh catalyzed hydroformylation as part of the Ruhrchemie/Rhone-Poulenc process has become the first commercially viable technique using aqueous catalyst solutions.
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页码：177 / 186
页数：10
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