UNUSUAL DENITROHYDROGENATION OF ALLYLIC TERTIARY NITRO-COMPOUNDS DURING HYDROGENATION

被引：6

作者：

BAJPAI, LK

BATRA, S

BHADURI, AP

机构：

[1] Division of Medicinal Chemistry, Central Drug Research Institute

来源：

SYNTHETIC COMMUNICATIONS | 1995年 / 25卷 / 12期

关键词：

D O I：

10.1080/00397919508015418

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Unusual denitrohydrogenations of alpha, alpha-disubstituted nitromethylcycloalk-1-enes during their hydrogenation in the presence of Pd-C have been reported. The possible mechanism of action has been suggested.

引用

页码：1765 / 1775

页数：11

共 12 条

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[2] SUBSTITUTION-REACTIONS WHICH PROCEED VIA RADICAL-ANION INTERMEDIATES .20. REPLACEMENT OF THE NITRO-GROUP BY HYDROGEN
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TAMURA, R
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[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (08) : 2851 - 2852
[6] 1-BENZYL-1,4-DIHYDRONICOTINAMIDE AS A REAGENT FOR REPLACING ALIPHATIC NITRO-GROUPS BY HYDROGEN - AN ELECTRON-TRANSFER CHAIN-REACTION
ONO, N
TAMURA, R
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[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (12) : 4017 - 4022
[7] ONO N, 1986, SYNTHESIS-STUTTGART, P693
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[9] ROSINI G, 1983, SYNTHESIS-STUTTGART, P137
[10] ROSINI G, 1988, SYNTHESIS-STUTTGART, P833

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