NEW TRENDS IN THE CHEMISTRY OF AROMATIC-COMPOUNDS WITH FLUORINE-CONTAINING SUBSTITUENTS

被引：12

作者：

YAGUPOLSKII, LM ^{[1
]}

YAGUPOLSKII, YL ^{[1
]}

机构：

[1] NATL ACAD SCI UKRAINE,INST ORGAN CHEM,DEPT ORGANFLUORINE COMPOUND CHEM,KIEV 253600,UKRAINE

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1995年 / 72卷 / 02期

关键词：

FLUORINE-CONTAINING AROMATICS; SUBSTITUENT EFFECTS; SUPERSTRONG ACIDS; SUPERSTRONG ELECTRON-WITHDRAW SUBSTITUENTS;

D O I：

10.1016/0022-1139(94)00411-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Recently, new methods for the introduction of fluorine-containing substituents into aromatic compounds have been developed in our Department and new types of organic substances synthesized. Emphasis has been placed not only on the 'classic' groups, such as the fluorine atom or perfluoro-aIkyl and -alkenyl fragments, but mainly on substituents with perfluoroalkyl groups separated from the nuclei by the heteroatoms oxygen, sulfur (in valency states 2, 4 and 6), nitrogen and metals. We have also developed new principles for the construction of super-strong electron-withdrawing substituents and superstrong acids. This approach consists in replacing the sp(2)-oxygen atom in various groups with the =NSO2CF3 radical and has been confirmed by examples of substituents with the central atoms consisting of sulfur in different valence states, carbon, phosphorus and iodine. From this principle, a stable substituent with sigma(p) constant 1.76, equal to three nitro groups in its influence toward benzene nuclei, has been constructed.

引用

页码：225 / 229

页数：5