THE BENZANNELATION APPROACH TO NOVEL GALLIUM AND INDIUM HETEROCYCLES

被引：19

作者：

DECKEN, A ^{[1
]}

GABBAI, FP ^{[1
]}

COWLEY, AH ^{[1
]}

机构：

[1] UNIV TEXAS,DEPT CHEM & BIOCHEM,AUSTIN,TX 78712

来源：

INORGANIC CHEMISTRY | 1995年 / 34卷 / 15期

关键词：

D O I：

10.1021/ic00119a002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first gallafluorene (1) has been prepared by two routes: (i) the reaction of Ar*GaC1(2) (Ar* = 2,4,6-t-Bu(3)C(6)H(2)) With 2,2'-dilithiobiphenyl (2), and (ii) the reaction of 2 with GaC1(3) followed by treatment with Ar*Li. The analogous indafluorene (4) has been prepared via the reaction of Ar*InBr2 with 2 . 2TMEDA. The structure of 1 has been determined by X-ray crystallography.

引用

收藏

页码：3853 / 3854

页数：2

相关论文

共 20 条

[1] THE SYNTHESIS AND STRUCTURE OF STIBAINDOLES [J].

BUCHWALD, SL ;

FISHER, RA ;

FOXMAN, BM .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1990, 29 (07) :771-772

[2] STRUCTURAL TRANSITION IN POLYPHENYLS .5. BIPHENYL - 3-DIMENSIONAL DATA AND NEW REFINEMENT AT 293 K [J].

CHARBONNEAU, GP ;

DELUGEARD, Y .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1977, 33 (MAY13) :1586-1588

[3] SYNTHESIS AND STRUCTURE OF [(CH2)(4)GA-MU-AS(T)BU(2)](2) - THE FIRST EXAMPLE OF A GALLACYCLOPENTANE [J].

COWLEY, AH ;

CORBELIN, S ;

JONES, RA ;

LAGOW, RJ ;

NAIL, JW .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 464 (01) :C1-C3

[4]

COWLEY AH, 1994, ANGEW CHEM INT EDIT, V33, P1370, DOI 10.1002/anie.199413701

[5] METALLACYCLE TRANSFER FROM ZIRCONIUM TO MAIN-GROUP ELEMENTS - A VERSATILE SYNTHESIS OF HETEROCYCLES [J].

FAGAN, PJ ;

NUGENT, WA ;

CALABRESE, JC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (05) :1880-1889

[6] SYNTHESIS OF MAIN GROUP HETEROCYCLES BY METALLACYCLE TRANSFER FROM ZIRCONIUM [J].

FAGAN, PJ ;

NUGENT, WA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (07) :2310-2312

[7] A SILICON ANALOG OF 9,9-DIPHENYLFLUORENE [J].

GILMAN, H ;

GORSICH, RD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1955, 77 (23) :6380-6381

[8]

HERBERICH GE, 1994, J ORGANOMET CHEM, V461, P21

[9] (PENTAPHENYL)ALUMINACYCLOPENTADIENE AS A COMPLEXING LIGAND - MOLECULAR-STRUCTURE OF (PENTAPHENYL)ALUMINACYCLOPENTADIENE AND ITS COMPLEX WITH 1,5-CYCLOOCTADIENENICKEL [J].

KRUGER, C ;

SEKUTOWSKI, JC ;

HOBERG, H ;

KRAUSEGOING, R .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1977, 141 (02) :141-148

[10]

MORRIS JH, 1982, COMPREHENSIVE ORGANO, V1, pCH5