RYDBERG STATES OF ACETYLENE CLUSTERS (C2H2)2 AND (C2H2)3 RESOLVED BY 2-PHOTON RESONANT IONIZATION SPECTROSCOPY

被引:11
|
作者
ZHU, YF [1 ]
ALLMAN, SL [1 ]
PHILLIPS, RC [1 ]
GARRETT, WR [1 ]
CHEN, CH [1 ]
机构
[1] OAK RIDGE NATL LAB, POB 2008, BLDG 5500 MS-6378, OAK RIDGE, TN 37831 USA
关键词
D O I
10.1016/0009-2614(94)00529-X
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The Rydberg states of the acetylene clusters (C2H2)2 and (C2H2)3 have been resolved by the technique of two-photon resonant ionization spectroscopy in the energy region of the monomer gerade Rydberg states. The stability of these cluster Rydberg states has been found to be vibrational mode dependent. The geometry of the clusters, and the mechanism of the dissociative ionization have been discussed.
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页码:7 / 15
页数:9
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