CONJUGATE ADDITION TO CHIRAL GAMMA-HETEROSUBSTITUTED DELTA-LACTONES AS PIVOTAL SYNTHONS FROM L-GLUTAMIC ACID - SYNTHESIS OF AN OPTICALLY-ACTIVE LIGNAN LACTONE - (-)-HINOKININ

被引:37
作者
YODA, H [1 ]
NAITO, S [1 ]
TAKABE, K [1 ]
TANAKA, N [1 ]
HOSOYA, K [1 ]
机构
[1] KYOTO INST TECHNOL,FAC TEXT SCI,KYOTO 606,JAPAN
关键词
D O I
10.1016/S0040-4039(00)97315-5
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Asymmetric induction in conjugate addition of new chiral gamma-heterosubstituted-alpha, beta-unsaturated sigma-lactones from L-glutamic acid was accomplished in high diasteroselectivity with the formation of trans-(R,S)-adducts and was disclosed to serve as a versatile procedure for the asymmetric synthesis of antileukemic lignan lactones.
引用
收藏
页码:7623 / 7626
页数:4
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