A NEW ROUTE TO EARLY-LATE HETEROBIMETALLIC MU-ALKYLIDENE COMPLEXES

被引:5
|
作者
CASEY, CP
ASKHAM, FR
PETROVICH, LM
机构
[1] Department of Chemistry, University of Wisconsin, Madison
基金
美国国家科学基金会;
关键词
D O I
10.1016/0022-328X(90)87188-J
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The reaction of two equivalents of Cp2ZrHCl (1) with Cp(CO)2ReCHR (2, R = CH2CH2CMe3; 4, R = CH3) led to the formation of the heterobimetallic μ-alkylidene complexes Cp2Zr(μ-CHR)(μ,η1,η2-CO)Re(CO)Cp (3, R = CH2CH2CMe3; 5, R = CH3). © 1990.
引用
收藏
页码:C31 / C35
页数:5
相关论文
共 50 条
  • [21] NOVEL REACTIONS OF PHOSPHORUS YLIDES WITH CARBONYL(CYCLOPENTADIENYL)METAL COMPLEXES - PREPARATIVE ACCESS TO MU-ALKYLIDENE COMPLEXES AND UNEXPECTED ACYLATIONS
    KORSWAGEN, R
    ALT, R
    SPETH, D
    ZIEGLER, ML
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1981, 20 (12): : 1049 - 1051
  • [22] Palladium-catalyzed allylic alkylations via titanated nucleophiles: A new early-late heterobimetallic system
    Poli, G
    Giambastiani, G
    Mordini, A
    JOURNAL OF ORGANIC CHEMISTRY, 1999, 64 (08) : 2962 - 2965
  • [23] Synthesis, reactivity, and catalytic activity of triangular ZrM2 (M = Rh, Ir) early-late heterobimetallic complexes
    Hernandez-Gruel, MAF
    Pérez-Torrente, JJ
    Ciriano, MA
    Rivas, AB
    Lahoz, FJ
    Dobrinovitch, IT
    Oro, LA
    ORGANOMETALLICS, 2003, 22 (06) : 1237 - 1249
  • [24] A New Route to Ruthenium Thiolate Alkylidene Complexes
    Dahcheh, Fatme
    Stephan, Douglas W.
    ORGANOMETALLICS, 2013, 32 (19) : 5253 - 5255
  • [25] Fulvalenediyl-bridged heterobimetallic complexes consisting of sandwich and half-sandwich compounds with early-late transition metals
    Jakob, Alexander
    Ecorchard, Petra
    Rueffer, Tobias
    Linseis, Michael
    Winter, Rainer F.
    Lang, Heinrich
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2009, 694 (22) : 3542 - 3547
  • [26] Atom-transfer within the coordination sphere of early-late heterobimetallic complexes:: rapid deoxygenation of sulfoxides at low temperatures
    Fabre, S
    Findeis, B
    Trösch, DJM
    Gade, LH
    Scowen, IJ
    McPartlin, M
    CHEMICAL COMMUNICATIONS, 1999, (07) : 577 - 578
  • [27] Synthesis and characterization of tantalum-based early-late heterobimetallic complexes supported by 2-(diphenylphosphino) pyrrolide ligands
    Dunn, Peter L.
    Beaumier, Evan P.
    Tonks, Ian A.
    POLYHEDRON, 2020, 181
  • [28] Catalytic H/D exchange of (hetero)arenes with early-late polyhydride heterobimetallic complexes: impact of transition metal pairs
    Lachguar, Abdelhak
    Neumann, Till
    Pichugov, Andrey V.
    Jeanneau, Erwann
    Veyre, Laurent
    Thieuleux, Chloe
    Camp, Clement
    DALTON TRANSACTIONS, 2025, 54 (09) : 3804 - 3811
  • [29] Catalytic Applications of Early/Late Heterobimetallic Complexes
    Cooper, Benjamin G.
    Napoline, J. Wesley
    Thomas, Christine M.
    CATALYSIS REVIEWS-SCIENCE AND ENGINEERING, 2012, 54 (01): : 1 - 40
  • [30] Early-late heterobimetallic alkoxides as model systems for late-transition-metal catalysts supported on titania
    Fandos, R
    Hernández, C
    Otero, A
    Rodríguez, A
    Ruiz, MJ
    Terreros, P
    CHEMISTRY-A EUROPEAN JOURNAL, 2003, 9 (03) : 671 - 677