LIGHT AND HEAVY EXCITONIC POLARONS IN CONJUGATED POLYMERS

被引：37

作者：

MAHRT, RF ^{[1
]}

BASSLER, H ^{[1
]}

机构：

[1] UNIV MARBURG,ZENTRUM MAT WISSENSCHAFT,W-3550 MARBURG,GERMANY

来源：

SYNTHETIC METALS | 1991年 / 45卷 / 01期

关键词：

D O I：

10.1016/0379-6779(91)91850-A

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The steady state fluorescence spectra of members of the poly(arylenevinylene) family as well as of poly(dodecylthiophene) have been measured employing the site selection technique. It allows the recovery of the fluorescence spectra of chromophores unaffected by spectral diffusion. In all cases the exciton picture is found appropriate for analysing the luminescence properties. The exciton is dressed by a structural deformation (excitonic polaron), the main contribution to the relaxation being torsional motion within the conjugated backbone.

引用

页码：107 / 117

页数：11

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