1,1'BIS(DIPHENYLTHIOPHOSPHORYL)FERROCENE AS A TRANS-CHELATING LIGAND IN GOLD(I) AND SILVER(I) COMPLEXES

被引：28

作者：

GIMENO, MC

JONES, PG

LAGUNA, A

SARROCA, C

机构：

[1] UNIV ZARAGOZA,CSIC,INST CIENCIA MAT ARAGON,DEPT QUIM INORGAN,E-50009 ZARAGOZA,SPAIN

[2] TECH UNIV CAROLO WILHELMINA BRAUNSCHWEIG,INST ANORGAN & ANALYT CHEM,D-38023 BRAUNSCHWEIG,GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1995年 / 21期

关键词：

D O I：

10.1039/dt9950003563

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of 1,1'-bis(diphenylthiophosphoryl)ferrocene (dptpf) with AgClO4 or [Au(tht)(2)]CF3SO3 (tht = tetrahydrothiophene) in a 1 : 1 molar ratio led to complexes of the stoichiometry [M(dptpf)(+) The crystal structures of both complexes revealed a linear co-ordination geometry with a novel trans co-ordination by the ligand.

引用

页码：3563 / 3564

页数：2