PERMEABILITY FOR REACTION H+H2=H2+H TREATED AS A LINEAR ENCOUNTER USING VARIATIONAL TECHNIQUES

被引：20

作者：

MORTENSEN, EM

GUCWA, LD

机构：

[1] Department of Chemistry, University of Massachusetts, Amherst

[2] Department of Chemistry, Cleveland State University, Cleveland

[3] Department of Chemistry, Arizona State University, Tempe

来源：

JOURNAL OF CHEMICAL PHYSICS | 1969年 / 51卷 / 12期

关键词：

D O I：

10.1063/1.1672000

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Variational calculations for determining the permeability of the Sato potential-energy surface as described by Weston have been made for the reaction H+H2=H2+H treated as a linear encounter. The results compare favorably with the corresponding calculations of Mortensen and Pitzer. The variational functions describing the asymptotic regions have a form after that of Kohn.

引用

页码：5695 / +

页数：1

共 14 条

[1]

Demkov Y.N., 1963, VARIATIONAL PRINCIPL

[2] QUANTUM-MECHANICAL TREATMENT OF INELASTIC COLLISIONS .2. EXCHANGE REACTIONS [J].