ALPHA-PALLADATED THIOAMIDES SIGMA-COMPLEXES OR PI-COMPLEXES

被引：12

作者：

TAMARU, Y ^{[1
]}

KAGOTANI, M ^{[1
]}

YOSHIDA, Z ^{[1
]}

机构：

[1] KYOTO UNIV,DEPT SYNTHET CHEM,KYOTO 606,JAPAN

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1979年 / 44卷 / 15期

关键词：

D O I：

10.1021/jo01329a056

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

α-Palladated thioamides (3) have been prepared by the addition reaction of soft carbonucleophiles to α,β-unsaturated thioamides in the presence of an equimolar amount of Pd(II). The structures of these yellow crystalline solids have been characterized by spectroscopic studies (1H NMR, 13C NMR, and IR) and chemical degradations (hydrogenation, carbonylation, base-induced cyclization to give dihydrofuran derivatives 8, etc.). © 1979, American Chemical Society. All rights reserved.

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页码：2816 / 2818

页数：3

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