KINETICS OF OXIDATION OF ORGANIC-COMPOUNDS BY SILVER(II) IN AQUEOUS PERCHLORIC-ACID SOLUTION .5.

被引：3
|
作者：
BAIOCCHI, C [1 ]
MENTASTI, E [1 ]
机构：
[1] UNIV TURIN,IST CHIM ANAL,I-10125 TURIN,ITALY
来源：
TRANSITION METAL CHEMISTRY | 1980年 / 5卷 / 05期
关键词：
547; Minor; Precious and Rare Earth Metals and Alloys - 802 Chemical Apparatus and Plants; Unit Operations; Unit Processes - 803 Chemical Agents and Basic Industrial Chemicals - 804 Chemical Products Generally;
D O I：
10.1007/BF01396932
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The kinetics and mechanism of oxidation of a series of alcohols, namely cyclohexanol, cyclopentanol, pentan-2-ol and benzyl alcohol, by silver(II) perchlorate in perchloric acid solution, have been investigated by the stopped-flow technique. These oxidations proceed through two parallel pathways involving Ag**2** plus and AgOH** plus species. In the case of benzyl alcohol, the hydroxo species, which has been found to be almost universally reactive toward different organic substrates, is inactive; this behavior has been interpreted in terms of interaction of the oxidant with the aromatic moiety in the alcohol.
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页码：259 / 262
页数：4
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