KINETICS OF OXIDATION OF ORGANIC-COMPOUNDS BY SILVER(II) IN AQUEOUS PERCHLORIC-ACID SOLUTION .5.

被引：3

作者：

BAIOCCHI, C ^{[1
]}

MENTASTI, E ^{[1
]}

机构：

[1] UNIV TURIN,IST CHIM ANAL,I-10125 TURIN,ITALY

来源：

TRANSITION METAL CHEMISTRY | 1980年 / 5卷 / 05期

关键词：

547; Minor; Precious and Rare Earth Metals and Alloys - 802 Chemical Apparatus and Plants; Unit Operations; Unit Processes - 803 Chemical Agents and Basic Industrial Chemicals - 804 Chemical Products Generally;

D O I：

10.1007/BF01396932

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The kinetics and mechanism of oxidation of a series of alcohols, namely cyclohexanol, cyclopentanol, pentan-2-ol and benzyl alcohol, by silver(II) perchlorate in perchloric acid solution, have been investigated by the stopped-flow technique. These oxidations proceed through two parallel pathways involving Ag**2** plus and AgOH** plus species. In the case of benzyl alcohol, the hydroxo species, which has been found to be almost universally reactive toward different organic substrates, is inactive; this behavior has been interpreted in terms of interaction of the oxidant with the aromatic moiety in the alcohol.

引用

页码：259 / 262

页数：4

共 10 条

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