SUPRAMOLECULAR CONTROL OF MOLECULAR ELECTRONIC BEHAVIOR OF TCNQ- SALTS

被引：15
作者：
GROSSEL, MC
WESTON, SC
机构：
[1] Department of Chemistry, University, Highfield, Southampton
来源：
JOURNAL OF PHYSICAL ORGANIC CHEMISTRY | 1992年 / 5卷 / 08期
关键词：
D O I：
10.1002/poc.610050816
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Crown ether complexation of 1:1 alkali metal TCNQ salts, MTCNQ (M = K, Rb, Tl) leads to structures containing isolated TCNQ dimers. These materials provide valuable models for investigating the spectroscopic and electronic behaviour of TCNQ-. dimer components which are key structural fragments of, for example, organic metals and semiconductors.
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页码：533 / 539
页数：7
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