COMPLEXES OF CARBOHYDRATES WITH METAL-CATIONS .15. COMPLEXING OF CARBOHYDRATES WITH COPPER IONS - A REAPPRAISAL

被引：42

作者：

ANGYAL, SJ

机构：

[1] School of Chemistry, University of New South Wales, Kensington

来源：

CARBOHYDRATE RESEARCH | 1990年 / 200卷

关键词：

D O I：

10.1016/0008-6215(90)84189-2

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Contrary to statements in the literature, Cu2+ ions form only weak complexes with polyols. At pH > 5, however, strong complex formation is observed which is attributed to [Cu2(OH)2]2+ or similar binuclear ions. The formation of tetradentate complexes is postulated with compounds having four hydroxyl groups in suitable steric relationship, especially alditols. © 1990.

引用

页码：181 / 188

页数：8

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