VIBRATIONAL ACTIVATION-ENERGY OF THE REACTION BR(P-2[3-2]) WITH CH3F

被引：6
作者：
KRASNOPYOROV, LN
CHESNOKOV, EN
PANFILOV, VN
机构：
[1] Institute of Chemical Kinetics and Combustion, USSR Academy of Sciences, Siberian Branch, Novosibirsk
来源：
CHEMICAL PHYSICS | 1979年 / 42卷 / 03期
关键词：
D O I：
10.1016/0301-0104(79)80083-X
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The influence of cw CO2-laser vibrational excitation of CH3F molecules on their reactions with bromine atoms, generated by light of various wavelengths, has been investigated. It was found that vibrational excitation accelerates the reaction Br(2P 3 2) + CH3F and does not influence the reaction Br(2P 3 2) + CH3F. The vibrational activation energy of Br(2P 3 2) + CH3F was found to be 12.5 ± 2.5 kcal mole-1. © 1979.
引用
收藏
页码：345 / 353
页数：9
相关论文
共 50 条
  • [41] A THEORETICAL-STUDY OF THE INFRARED VIBRATIONAL INTENSITIES OF CH3F
    SOSA, C
    SCHLEGEL, HB
    JOURNAL OF CHEMICAL PHYSICS, 1987, 86 (12) : 6937 - 6945
  • [42] DEPENDENCE OF THE VIBRATIONAL-RELAXATION RATE OF CH3F ON THE EQUILIBRIUM AND VIBRATIONAL TEMPERATURES
    CHESNOKOV, EN
    SHCHERBININA, VN
    PANFILOV, VN
    ZHURNAL EKSPERIMENTALNOI I TEORETICHESKOI FIZIKI, 1978, 75 (06): : 2066 - 2074
  • [43] OBSERVATION OF THE P-2(1/2)]-P-2(3/2) TRANSITION OF THE BR ATOM BY COLOR CENTER LASER SPECTROSCOPY
    KASPER, JVV
    POLLOCK, CR
    CURL, RF
    TITTEL, FK
    CHEMICAL PHYSICS LETTERS, 1981, 77 (01) : 211 - 213
  • [44] Reactivity of the ground and excited spin-orbit states for the reaction of the F(P-2(3/2),P-2(1/2)) with D-2
    Zhang, Y
    Xie, TM
    Han, KL
    JOURNAL OF PHYSICAL CHEMISTRY A, 2003, 107 (50) : 10893 - 10896
  • [45] A DFT study on the reaction of O- with CH3F
    Yamamoto, M
    Yamashita, K
    Sadakata, M
    JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM, 2003, 634 : 31 - 39
  • [46] DEACTIVATION OF HBR (UPSILON = 1) BY BR (P-2 3/2) ATOMS
    KARNY, Z
    KATZ, B
    CHEMICAL PHYSICS, 1976, 14 (02) : 295 - 299
  • [47] ROVIBRATIONAL AVERAGING OF MOLECULAR MAGNETIC-PROPERTIES OF CH3F, CH2F2, AND CHF3
    JAMESON, CJ
    OSTEN, HJ
    MOLECULAR PHYSICS, 1985, 56 (05) : 1083 - 1095
  • [48] Measurements and modeling of N2-broadening coefficients for the ν6 band of CH3F, comparison with CH3Cl and CH3Br molecules
    Ramchani, A. Barbouchi
    Jacquemart, D.
    Soulard, P.
    Guinet, M.
    JOURNAL OF QUANTITATIVE SPECTROSCOPY & RADIATIVE TRANSFER, 2017, 203 : 480 - 489
  • [49] A MASS-SPECTROMETRIC PHOTOIONIZATION STUDY OF CH3F - THE CH-2+, CH-3+ AND CH2F+ ION FORMATION
    LOCHT, R
    MOMIGNY, J
    RUHL, E
    BAUMGARTEL, H
    CHEMICAL PHYSICS, 1987, 117 (02) : 305 - 313
  • [50] INTRAMOLECULAR VIBRATIONAL ENERGY-TRANSFER IN 1B2 ANILINE INDUCED BY COLLISIONS WITH H2O AND CH3F
    VANDERSALL, M
    CHERNOFF, DA
    RICE, SA
    JOURNAL OF CHEMICAL PHYSICS, 1981, 74 (09) : 4888 - 4892
12345