VIBRATIONAL ACTIVATION-ENERGY OF THE REACTION BR(P-2[3-2]) WITH CH3F

被引：6
|
作者：
KRASNOPYOROV, LN
CHESNOKOV, EN
PANFILOV, VN
机构：
[1] Institute of Chemical Kinetics and Combustion, USSR Academy of Sciences, Siberian Branch, Novosibirsk
来源：
CHEMICAL PHYSICS | 1979年 / 42卷 / 03期
关键词：
D O I：
10.1016/0301-0104(79)80083-X
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The influence of cw CO2-laser vibrational excitation of CH3F molecules on their reactions with bromine atoms, generated by light of various wavelengths, has been investigated. It was found that vibrational excitation accelerates the reaction Br(2P 3 2) + CH3F and does not influence the reaction Br(2P 3 2) + CH3F. The vibrational activation energy of Br(2P 3 2) + CH3F was found to be 12.5 ± 2.5 kcal mole-1. © 1979.
引用
收藏
页码：345 / 353
页数：9
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