SYNTHESIS AND CRYSTAL-STRUCTURE OF CU0.25HO1.25W2O8

被引：2

作者：

SZILLAT, H ^{[1
]}

MULLERBUSCHBAUM, H ^{[1
]}

机构：

[1] CHRISTIAN ALBRECHTS UNIV KIEL,INST ANORGAN CHEM,D-24098 KIEL,GERMANY

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1994年 / 49卷 / 08期

关键词：

CRYSTAL STRUCTURE; COPPER; HOLMIUM; TUNGSTEN; OXIDE;

D O I：

10.1515/znb-1994-0821

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Single crystals of Cu0.25Ho1.25W2O8 were prepared by recrystallization from melts and investigated by X-ray diffractometer technique. Cu0.25Ho1.25W2O8 crystallizes with monoclinic symmetry, space group C2/c, n = 19.123, b = 5.613, c = 11.479 Angstrom, beta = 111.44 degrees, Z = S. It represents a new structure type characterized by W4O18 groups and Cu+/Ho3+ at one point position in statistical distribution. Cu+/Ho3+ show an octahedral coordination. Another point position is occupied by Ho3+ with C.N. = 7.

引用

页码：1145 / 1149

页数：5

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