A MODEL-COMPOUND FOR THE INTERACTION OF THALLIUM(I) WITH NUCLEOBASES - CRYSTAL AND MOLECULAR-STRUCTURE OF (NITRATO)(1-METHYLCYTOSINE)THALLIUM(I)

被引：18
作者：
RENN, O [1 ]
PREUT, H [1 ]
LIPPERT, B [1 ]
机构：
[1] UNIV DORTMUND,DEPT CHEM,W-4600 DORTMUND 50,GERMANY
来源：
INORGANICA CHIMICA ACTA | 1991年 / 188卷 / 02期
关键词：
D O I：
10.1016/S0020-1693(00)80362-X
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of 1-methylcytosine with TlNO3 in variable ratios gave crystals of the 1:1 complex, Tl(C5H7N3O)NO3. The crystal structure of the title compound, which represents the first example of a nucleobase complex with Tl(I), has been performed. C5H7N4O4Tl crystallizes in the triclinic system, space group P1BAR, with cell dimensions a = 3.786(2), b = 10.804(5), c = 11.508(5) angstrom, alpha = 105.02(3), beta = 92.37(4), gamma = 98.24(4)-degrees, U = 448.4(4) angstrom 3, Z = 2.
引用
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页码：133 / 137
页数：5
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