Thermal decomposition of butylindium thiolates and preparation of indium sulfide powders

被引：70

作者：

Nomura, Ryoki ^{[1
]}

Inazawa, Shin'ji ^{[1
]}

Kanaya, Kouichi ^{[1
]}

Matsuda, Haruo ^{[1
]}

机构：

[1] Osaka Univ, Fac Engn, Dept Appl Chem, Suita, Osaka 565, Japan

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 1989年 / 3卷 / 02期

关键词：

Organoindium thiolates; thermal decomposition; indium sulfide powders; optoelectronic materials; vapor deposition;

D O I：

10.1002/aoc.590030213

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Thermal properties of organoindium thiolates were investigated by means of thermogravimetric (TG) and differential thermal (DT) analysis. Dibutyl-indium propylthiolates ((Bu2InSPrn)-In-n, (Bu2InSPri)-In-n, (Bu2InSPrn)-In-i and Bu(2)(i)InSPri) decomposed up to 280 degrees C along with an exothermic DT peak and gave indium(I) sulfide (Ins) powders. Although the arylthiolate (Bu2InSPh)-In-n also afforded Ins powders, it decomposed at a slightly higher temperature. In contrast, the dithiolate and the dithiocarbamate complexes [(BuIn)-In-n(SPri)(2) and (S2CNB2)(3)] gave indium(III) sulfide (In2S3) powders.

引用

页码：195 / 197

页数：3

共 6 条

[1] OPTICAL-ENERGY GAPS OF BETA-IN2S3 THIN-FILMS GROWN BY SPRAY PYROLYSIS [J].

KIM, WT ;

KIM, CD .

JOURNAL OF APPLIED PHYSICS, 1986, 60 (07) :2631-2633

[2] FACILE SYNTHESIS OF ANTIMONY DITHIOCARBAMATE COMPLEXES [J].

NOMURA, R ;

TAKABE, A ;

MATSUDA, H .

POLYHEDRON, 1987, 6 (03) :411-416

[3] THERMAL-DECOMPOSITION OF ORGANOINDIUM COMPOUNDS AND PREPARATION OF INDIUM TIN-OXIDE FILMS [J].

NOMURA, R ;

INAZAWA, S ;

MATSUDA, H ;

SAEKI, S .

POLYHEDRON, 1987, 6 (03) :507-512

[4]

Nomura R, 1986, 52 ANN M CHEM SOC SO

[5] ELECTRONIC BAND-STRUCTURE AND OPTICAL ANISOTROPY IN INS .1. EXPERIMENTAL-STUDY [J].

TAKARABE, K ;

KAWAMURA, H ;

WAKAMURA, K .

PHYSICA STATUS SOLIDI B-BASIC RESEARCH, 1987, 142 (02) :605-615

[6] ANALYSIS OF THE PHOTOVOLTAIC PROPERTIES OF SPRAYED CUINS2/SNOX-F SOLAR-CELLS [J].

TIWARI, AN ;

PANDYA, DK ;

CHOPRA, KL .

SOLAR ENERGY MATERIALS, 1987, 15 (02) :121-133

← 1 →