Calculation of the isotope effect on the triplet lifetime of partially deuterated naphthaleness

被引：27

作者：

Henry, B. R. ^{[1
]}

Siebrand, W. ^{[1
]}

机构：

[1] Natl Res Council Canada, Div Pure Chem, Ottawa, ON, Canada

来源：

CHEMICAL PHYSICS LETTERS | 1969年 / 3卷 / 05期

基金：

英国医学研究理事会;

关键词：

D O I：

10.1016/0009-2614(69)80244-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Differences in triplet lifetime between alpha and beta deuterated naphthalenes are calculated in good agreement with experiment. The calculation is based on vibronic spin-orbit coupling involving sigma pi* and pi sigma* states together with CH out-of-plane bending modes.

引用

页码：327 / 328

页数：2

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