MASS-TRANSPORT IN THE PRESENCE OF INTERNAL DEFECT REACTIONS - CONCEPT OF CONSERVATIVE ENSEMBLES .2. EVALUATION OF ELECTROCHEMICAL TRANSPORT MEASUREMENTS

被引：41

作者：

MAIER, J

机构：

[1] Max-Planck-Institut fur Festkörperforschung, Stuttgart

来源：

JOURNAL OF THE AMERICAN CERAMIC SOCIETY | 1993年 / 76卷 / 05期

关键词：

D O I：

10.1111/j.1151-2916.1993.tb03744.x

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

It is shown that in the general case of a defective solid, where the ionic point defects can change their valence states, the evaluation formulas of well-known-electrochemical techniques (such as concentration cell experiments, Wagner-Hebb method, chemical and electrochemical polarization and relaxation) have to be modified. The generalized relationships are derived.

引用

页码：1218 / 1222

页数：5

共 23 条

[1]

Carslaw HS, 1988, CONDUCTION HEAT SOLI

[2]

Crank J., 1970, MATH DIFFUSION

[3]

DUDLEY FJ, 1980, J SOLID STATE CHEM, V10, P233

[4]

HAUFFE K, 1966, REAKTIONEN FESTEN ST