Hydrogenation reaction of carbonyl compounds catalyzed by cationic ruthenium complexes

被引：0
作者：
Inagaki, H
Nishimura, S
Hara, Y
Wada, K
机构：
来源：
SCIENCE AND TECHNOLOGY IN CATALYSIS 1994 | 1995年 / 92卷
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中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A ruthenium complex prepared from Ru(acac)(3), trioctylphosphine, and phosphoric acid ester showed high activity and selectivity in hydrogenation of succinic anhydride to 1,4-butanediol. The structure of the complex was assigned to be [RuH(H-2)(PR(3))(3)S]X or [RuH(PR(3))(3)S-2]X (S=solvent) which was more active than the neutral ruthenium complexes obtained from Ru(acac)(3) and trioctylphosphine without phosphoric acid esters.
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页码：327 / 330
页数：4
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