SYNTHESIS, PHOTOPHYSICAL PROPERTIES AND CRYSTAL-STRUCTURE OF TETRA-N-BUTYLAMMONIUM BIS(MALEONITRILEDITHIOLATO)-NITRIDOOSMATE(VI)

被引：12

作者：

LEUNG, WH ^{[1
]}

WU, MC ^{[1
]}

CHE, CM ^{[1
]}

WONG, WT ^{[1
]}

CHIN, KF ^{[1
]}

机构：

[1] UNIV HONG KONG, DEPT CHEM, HONG KONG, HONG KONG

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1994年 / 17期

关键词：

D O I：

10.1039/dt9940002519

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of [NBun4] [OsNCl4] with 2 equivalents of Na2(mnt) (mnt = maleonitriledithiolate) gave [NBun4][OsN(mnt)2] 1 in good yield. The structure of 1 has been confirmed by an X-ray diffraction analysis, Os = N being 1.639(8) angstrom. The complex shows emission from the 3[(d(xy))(d(pi.))] excited state.

引用

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页码：2519 / 2521

页数：3

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