SYNTHESIS, PHOTOPHYSICAL PROPERTIES AND CRYSTAL-STRUCTURE OF TETRA-N-BUTYLAMMONIUM BIS(MALEONITRILEDITHIOLATO)-NITRIDOOSMATE(VI)

被引：12
|
作者：
LEUNG, WH [1 ]
WU, MC [1 ]
CHE, CM [1 ]
WONG, WT [1 ]
CHIN, KF [1 ]
机构：
[1] UNIV HONG KONG, DEPT CHEM, HONG KONG, HONG KONG
来源：
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1994年 / 17期
关键词：
D O I：
10.1039/dt9940002519
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Treatment of [NBun4] [OsNCl4] with 2 equivalents of Na2(mnt) (mnt = maleonitriledithiolate) gave [NBun4][OsN(mnt)2] 1 in good yield. The structure of 1 has been confirmed by an X-ray diffraction analysis, Os = N being 1.639(8) angstrom. The complex shows emission from the 3[(d(xy))(d(pi.))] excited state.
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页码：2519 / 2521
页数：3
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