IONIC TRANSPORT IN POLY(ETHYLENE OXIDE) (PEO)-LIX POLYMERIC SOLID ELECTROLYTE

被引：50
作者：
MUNSHI, MZA
OWENS, BB
机构：
[1] Univ of Minnesota, United States
来源：
POLYMER JOURNAL | 1988年 / 20卷 / 07期
关键词：
Electrolytes; Solid - Lithium Compounds - Organometallics--Ionic Conduction - Salts;
D O I：
10.1295/polymj.20.577
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The ionic conductivity behavior of poly(ethylene oxide) complexed with lithium salts was investigated using an a.c. impedance technique. The composition range of the salt was from 0.01 to 0.5 mole fraction. The result showed that anions strongly influence the conductivity behavior of the polymer electrolyte. A simple model is proposed whereby the conductivity decrease at higher salt concentration is due to ion-pair formation. This results in an increase in the activation energy with increasing salt concentration and a reduction in the ionic mobility of Li+ ions.
引用
收藏
页码：577 / 586
页数：10
相关论文
共 37 条
  • [1] Armand M. B., 1979, Fast Ion Transport in Solids. Electrodes and Electrolytes, P131
  • [2] ARMAND MB, 1978, 2 INT M SOL EL ST AN
  • [3] THE CRYSTAL STRUCTURE OF NAALCL4
    BAENZIGER, NC
    [J]. ACTA CRYSTALLOGRAPHICA, 1951, 4 (03): : 216 - 219
  • [4] BELLANCA A, 1951, REND SOC MINERAL ITA, V7, P42
  • [5] MICROSCOPIC INVESTIGATION OF IONIC-CONDUCTIVITY IN ALKALI-METAL SALTS POLY(ETHYLENE OXIDE) ADDUCTS
    BERTHIER, C
    GORECKI, W
    MINIER, M
    ARMAND, MB
    CHABAGNO, JM
    RIGAUD, P
    [J]. SOLID STATE IONICS, 1983, 11 (01) : 91 - 95
  • [6] BLOMGREN GE, 1900, P ELECTROCHEM SOC PR, V804, P368
  • [7] BLOMGREN GE, 1983, LITHIUM BATTERIES, P38
  • [8] COMPLEX-FORMATION AND IONIC-CONDUCTIVITY OF POLYPHOSPHAZENE SOLID ELECTROLYTES
    BLONSKY, PM
    SHRIVER, DF
    AUSTIN, P
    ALLCOCK, HR
    [J]. SOLID STATE IONICS, 1986, 18-9 (pt 1) : 258 - 264
  • [9] BODE H, 1955, ACTA CRYSTALLOGR, V8, P661
  • [10] POLYMERIC ELECTROLYTE BASED ON POLY(ETHYLENE IMINE) AND LITHIUM-SALTS
    CHIANG, CK
    DAVIS, GT
    HARDING, CA
    TAKAHASHI, T
    [J]. SOLID STATE IONICS, 1986, 18-9 (pt 1) : 300 - 305
1234