ORGANIC SYNTHESES BY MEANS OF NOBLE METAL COMPOUNDS .40. PALLADIUM-CATALYSED CARBONYLATION OF ALLYLIC ETHERS

被引：12
作者：
IMAMURA, S
TSUJI, J
机构：
[1] Basic Research Laboratories, Toyo Rayon Co., Ltd. Kamakura
来源：
TETRAHEDRON | 1969年 / 25卷 / 18期
关键词：
D O I：
10.1016/S0040-4020(01)82955-0
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Palladium catalysed carbonylation of allylic ethers, especially 1,4-diethoxy-2-butene has been carried out. Hexenedioate, 5-ethoxy-3-pentenoate, 2-ethoxymethyl-3-butenoate, 3-pentenoate, pentadienoate were obtained and the mechanism of the allylic carbonylation and competing reactions are discussed. © 1969.
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页码：4187 / &
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