ORGANOTIN COMPOUNDS WITH 1-METHYL-2(3 H)-IMIDAZOLINETHIONE - THE CRYSTAL AND MOLECULAR-STRUCTURE OF DICHLOROBIS[1-METHYL-2(3H)-IMIDAZOLINETHIONE]DIPHENYLTIN(IV)

被引：17

作者：

MARTINEZ, EG

GONZALEZ, AS

CASAS, JS

SORDO, J

CASELLATO, U

GRAZIANI, R

RUSSO, U

机构：

[1] UNIV SANTIAGO COMPOSTELA,DEPT QUIM INORGAN,E-15706 SANTIAGO,SPAIN

[2] CNR,IST CHIM & TECNOL RADIOELEMENTI,I-35020 PADUA,ITALY

[3] UNIV PADUA,DIPARTIMENTO CHIM INORGAN METALLORG & ANALIT,I-35131 PADUA,ITALY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 463卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)83403-I

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The compounds [SnPh(2)Cl(2)(Hmimt)], [SnPh(2)Cl(2)(Hmimt)(2)] and (Et(4)N)[SnPh(2)Cl(3)(Hmimt)] (Hmimt = 1-methyl-2(3H)-imidazolinethione) have been prepared and characterized by conductivity measurements and by IR, Raman, mass, Mossbauer and H-1, C-13, and Sn-119 NMR spectroscopies. The structure of the all-trans-octahedral [SnPh(2)Cl(2)(Hmimt)(2)] complex was determined by X-ray crystallography. Coordination bond lengths (Angstrom) are: Sn-Cl 2.587(1), Sn-C 2.154(3) and Sn-S 2.705(1).

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页码：91 / 96

页数：6

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