COMPLEXATION WITH HYDROXY HOST COMPOUNDS .1. STRUCTURES AND THERMAL-ANALYSIS OF A SUBEROL-DERIVED HOST AND ITS HOST GUEST COMPLEXES WITH DIOXANE AND ACETONE

被引：41

作者：

CAIRA, MR

NASSIMBENI, LR

NIVEN, ML

SCHUBERT, WD

WEBER, E

DORPINGHAUS, N

机构：

[1] UNIV CAPE TOWN,DEPT CHEM,RONDEBOSCH 7700,SOUTH AFRICA

[2] UNIV BONN,INST ORGAN CHEM & BIOCHEM,W-5300 BONN,GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1990年 / 12期

关键词：

D O I：

10.1039/p29900002129

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The title host compound, 10,11-dihydro-5-phenyl-5H-dibenzo[a,d]cyclohepten-5-ol 1, crystallizes in the non-porous alpha-phase without hydrogen bonding. The beta-phases of its dioxane 2 and acetone 3 complexes are stabilized by hydrogen bonds between host and guest. Thermal analysis of the two inclusion compounds gives qualitative correlation with their structures and a relative measure of their stabilities.

引用

页码：2129 / 2133

页数：5