COMPLEXATION WITH HYDROXY HOST COMPOUNDS .1. STRUCTURES AND THERMAL-ANALYSIS OF A SUBEROL-DERIVED HOST AND ITS HOST GUEST COMPLEXES WITH DIOXANE AND ACETONE

被引：41
作者：
CAIRA, MR
NASSIMBENI, LR
NIVEN, ML
SCHUBERT, WD
WEBER, E
DORPINGHAUS, N
机构：
[1] UNIV CAPE TOWN,DEPT CHEM,RONDEBOSCH 7700,SOUTH AFRICA
[2] UNIV BONN,INST ORGAN CHEM & BIOCHEM,W-5300 BONN,GERMANY
来源：
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1990年 / 12期
关键词：
D O I：
10.1039/p29900002129
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The title host compound, 10,11-dihydro-5-phenyl-5H-dibenzo[a,d]cyclohepten-5-ol 1, crystallizes in the non-porous alpha-phase without hydrogen bonding. The beta-phases of its dioxane 2 and acetone 3 complexes are stabilized by hydrogen bonds between host and guest. Thermal analysis of the two inclusion compounds gives qualitative correlation with their structures and a relative measure of their stabilities.
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页码：2129 / 2133
页数：5
相关论文
共 21 条
[1]   TABLES OF BOND LENGTHS DETERMINED BY X-RAY AND NEUTRON-DIFFRACTION .1. BOND LENGTHS IN ORGANIC-COMPOUNDS [J].
ALLEN, FH ;
KENNARD, O ;
WATSON, DG ;
BRAMMER, L ;
ORPEN, AG ;
TAYLOR, R .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1987, (12) :S1-S19
[2]  
BOURNE S, 1989, UNPUB
[3]   RELATIVISTIC CALCULATION OF ANOMALOUS SCATTERING FACTORS FOR X-RAYS [J].
CROMER, DT ;
LIBERMAN, D .
JOURNAL OF CHEMICAL PHYSICS, 1970, 53 (05) :1891-&
[4]   X-RAY SCATTERING FACTORS COMPUTED FROM NUMERICAL HARTREE-FOCK WAVE FUNCTIONS [J].
CROMER, DT ;
MANN, JB .
ACTA CRYSTALLOGRAPHICA SECTION A-CRYSTAL PHYSICS DIFFRACTION THEORETICAL AND GENERAL CRYSTALLOGRAPHY, 1968, A 24 :321-&
[5]   Hydrogen-Bond Directed Cocrystallization as a Tool for Designing Acentric Organic Solids [J].
Etter, Margaret C. ;
Frankenbach, Gayle M. .
CHEMISTRY OF MATERIALS, 1989, 1 (01) :10-12
[6]   THE CALCULATION OF MOLECULAR VOLUMES AND THE USE OF VOLUME ANALYSIS IN THE INVESTIGATION OF STRUCTURED MEDIA AND OF SOLID-STATE ORGANIC-REACTIVITY [J].
GAVEZZOTTI, A .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (16) :5220-5225
[7]  
Lipkowski J., 1984, INCLUSION COMPOUNDS, V1
[8]  
MOTHERWELL WDS, 1974, PLUTO STRUCTURE PLOT
[9]   PARST - A SYSTEM OF FORTRAN ROUTINES FOR CALCULATING MOLECULAR-STRUCTURE PARAMETERS FROM RESULTS OF CRYSTAL-STRUCTURE ANALYSES [J].
NARDELLI, M .
COMPUTERS & CHEMISTRY, 1983, 7 (03) :95-98
[10]  
Pope M.T., 1983, HETEROPOLY ISOPOLY O
123