AMIDE METALATION REACTIONS - SYNTHESIS AND X-RAY CRYSTAL-STRUCTURES OF [RU(NHCOCF3)2(H2O)(CO)(PPH3)2], [PH3P)(OC)RU(MU-NHCOC6H4-OMICRON)(MU-NHCOPH)(MU-H)RU(CO)(PPH3)2] AND [RU2(MU-CL)(MU-H)(MU-NHCOCF3)2(PPH3)4]

被引：17

作者：

HURSTHOUSE, MB ^{[1
]}

MAZID, MA ^{[1
]}

ROBINSON, SD ^{[1
]}

SAHAJPAL, A ^{[1
]}

机构：

[1] UNIV LONDON KINGS COLL,DEPT CHEM,LONDON WC2R 2LS,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 17期

关键词：

D O I：

10.1039/c39910001146

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Amides, NH2COR (R = CF3, Ph), undergo metallation reactions to form mono- and bi-nuclear ruthenium(II) amido complexes, notably [Ru(NHCOCF3)2(H2O)(CO)(PPh3)2], the cyclometallated (N,C) benzamido derivative [Ph3P)(OC) activated Ru(mu-NHCOC6H4-o)(mu-NHCOPh)(mu-H)Ru(CO)(PPh3)2] and the quadruply bridged species [Ru2(mu-Cl)(mu-H)(mu-NHCOCF3)2(PPh3)4] all of which have been characterised by X-ray diffraction methods.

引用

页码：1146 / 1148

页数：3

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