SCHIFF-BASE COMPLEXES WITH 5-COORDINATE COBALT AS DIOXYGEN ACTIVATING SITES IN ZEOLITES

被引：48
|
作者：
DEVOS, DE [1 ]
THIBAULTSTARZYK, F [1 ]
JACOBS, PA [1 ]
机构：
[1] KATHOLIEKE UNIV LEUVEN,CTR SURFACE CHEM & CATALYSIS,B-3001 HEVERLEE,BELGIUM
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 04期
关键词：
D O I：
10.1002/anie.199404311
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Cages of cubic faujasite FAU and its hexagonal polymorph EMT can house Co2+ complexes of the pentadentate Schiff base smdpt (structure from computer simulations shown on the right). The influence of the framework topology on complexation was examined. In addition, these enclosed complexes can bind dioxygen reversibly as proved by ESR studies. H2smdpt = bis[3‐(salicylidenamino)propyl]methylamine. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany
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页码：431 / 433
页数：3
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