CHARACTERIZATION OF SILVER-RICH TERNARY OXIDES WITH PHOTOELECTRON-SPECTROSCOPY

被引：4

作者：

HEIDEBRECHT, K

JANSEN, M

KRAUSE, S

BRADSHAW, AM

机构：

[1] UNIV BONN,INST ANORGAN CHEM,GERHARD DOMAGK STR 1,W-5300 BONN,GERMANY

[2] MAX PLANCK GESELL,FRITZ HABER INST,W-1000 BERLIN 33,GERMANY

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 1990年 / 89卷 / 01期

关键词：

D O I：

10.1016/0022-4596(90)90293-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The silver-rich ternary oxides Ag6Si2O7, Ag10Si4O13, Ag6Ge2O7, and Ag10Ge4O13, as well as Ag2SO4, have been investigated with photoelectron spectroscopy. The Ag 3d core level binding energies in all four ternary oxides were found to be identical with that of Ag metal, compared to the small negative chemical shift observed in AgSO4 and most other silver compounds. The MgKα and HeI valence band spectra are both dominated by Ag 4d emission; at the lower photon energy O 2p-derived states are also observed. There is some evidence for a direct Ag 4d-O 2p interaction. © 1990.

引用

收藏

页码：60 / 66

页数：7

相关论文

共 19 条

[1] XPS - ENERGY CALIBRATION OF ELECTRON SPECTROMETERS .2. RESULTS OF AN INTERLABORATORY COMPARISON [J].

ANTHONY, MT ;

SEAH, MP .

SURFACE AND INTERFACE ANALYSIS, 1984, 6 (03) :107-115

[2] ELECTRONIC-STRUCTURES OF LITHIUM METASILICATE AND LITHIUM DISILICATE [J].

CHING, WY ;

LI, YP ;

VEAL, BW ;

LAM, DJ .

PHYSICAL REVIEW B, 1985, 32 (02) :1203-1207

[3] COMPARATIVE STUDIES OF ELECTRONIC-STRUCTURES OF SODIUM METASILICATE AND ALPHA-PHASE AND BETA-PHASE OF SODIUM DISILICATE [J].

CHING, WY ;

MURRAY, RA ;

LAM, DJ ;

VEAL, BW .

PHYSICAL REVIEW B, 1983, 28 (08) :4724-4735

[4] CORE-LEVEL BINDING-ENERGY SHIFTS AT SURFACES AND IN SOLIDS [J].

Egelhoff, W. F., Jr. .

SURFACE SCIENCE REPORTS, 1987, 6 (6-8) :253-415

[5] ELECTRONIC-STRUCTURE OF SIO2, SIXGE1-XO2, AND GEO2 FROM PHOTOEMISSION SPECTROSCOPY [J].

FISCHER, B ;

POLLAK, RA ;

DISTEFANO, TH ;

GROBMAN, WD .

PHYSICAL REVIEW B, 1977, 15 (06) :3193-3199

[6] LIGHT-ABSORPTION OF SILVER(I)-OXIDES [J].

FRIEBEL, C ;

JANSEN, M .

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1984, 39 (06) :739-743

[7] CORE-LEVEL BINDING-ENERGIES IN METALS [J].

FUGGLE, JC ;

MARTENSSON, N .

JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 1980, 21 (03) :275-281

[8] INITIAL AND FINAL-STATE EFFECTS IN ESCA SPECTRA OF CADMIUM AND SILVER-OXIDES [J].

GAARENSTROOM, SW ;

WINOGRAD, N .

JOURNAL OF CHEMICAL PHYSICS, 1977, 67 (08) :3500-3506

[9] SILVER PARTICLE STRUCTURES IN SILVER-OXIDES [J].

JANSEN, M .

JOURNAL OF THE LESS-COMMON METALS, 1980, 76 (1-2) :285-292

[10] HOMOATOMIC D10-D10 INTERACTIONS - THEIR EFFECTS ON STRUCTURE AND CHEMICAL AND PHYSICAL-PROPERTIES [J].

JANSEN, M .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1987, 26 (11) :1098-1110