COMPARISON OF THE EFFECTIVENESS OF SULFURIC-ACID AND TRIFLUORO-METHANESULFONIC ACID IN KOCH CARBOXYLATION REACTIONS

被引：44

作者：

BOOTH, BL

ELFEKKY, TA

机构：

[1] Department of Chemistry, University of Manchester, Institute of Science and Technology

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1979年 / 10期

关键词：

D O I：

10.1039/p19790002441

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Trifluoromethanesulphonic acid has been found to be far superior to 95% sulphuric acid for the carboxylation of olefins, alcohols, and esters with carbon monoxide at atmospheric pressure. This is attributed to the higher acidity of CF3SO3H and also the higher solubility of carbon monoxide in this acid. At higher carbon monoxide pressures the difference in behaviour of the two acids is much less marked as, under these conditions, the carbon monoxide concentration is not a limiting factor.

引用

页码：2441 / 2446

页数：6

共 33 条

[1]

Brouwer D.M., 1972, PROGR PHYSICAL ORGAN, V9, P179, DOI DOI 10.1002/9780470171882.CH4

[2] AROMATIC NITRATION WITH NITRIC-ACID AND TRIFLUOROMETHANESULFONIC ACID [J].