DEHYDROGENATION OF SECONDARY-ALCOHOLS TO KETONES PROMOTED BY RHODIUM AND IRIDIUM CATALYSTS AND ALKALI

被引：26

作者：

FRAGALE, C ^{[1
]}

ROSSI, M ^{[1
]}

GARGANO, M ^{[1
]}

机构：

[1] UNIV BARI,IST CHIM GEN INORGAN,I-70124 BARI,ITALY

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1979年 / 5卷 / 01期

关键词：

D O I：

10.1016/0304-5102(79)80082-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Hydrogen transfer from sec-alcohols to alkenes, producing ketones and alkanes, has been studied using homogeneous systems containing the complexes MCl(C8H12)PPh3 (M = Rh and Ir), and heterogeneous systems containing Rh and Ir metals. Catalyst activity in the alcohol dehydrogenation has also been compared with that previously found in the reverse reaction of ketone hydrogenation. © 1979.

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页码：65 / 73

页数：9

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