BASE-FREE MONOMERIC ORGANOGALLIUM HYDRIDES

被引：26

作者：

COWLEY, AH ^{[1
]}

GABBAI, FP ^{[1
]}

ISOM, HS ^{[1
]}

CARRANO, CJ ^{[1
]}

BOND, MR ^{[1
]}

机构：

[1] SW TEXAS STATE UNIV,DEPT CHEM,SAN MARCOS,TX 78666

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 12期

关键词：

D O I：

10.1002/anie.199412531

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Stable tricoordinate mono‐ and dihydrides of gallium, 1 and [(Ar)Ga(H)2], respectively, can be isolated by taking advantage of the kinetic stabilization afforded by bulky Ar substituents. The monohydride 1, prepared from [(Ar)2GaCl] and Li‐GaH4, is the product of an unusual rearrangement reaction. Ar = 2,4,6‐tBuC6H2. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

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页码：1253 / 1255

页数：3

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