Redetermination of diaquatris(4-oxo-pent-2-en-2-olato-kappa O-2,O')lanthanum(III)

被引：2
作者：
Okawara, Toru [1 ]
Ishihama, Kohei [1 ]
Takehara, Kenji [1 ]
机构：
[1] Kitakyushu Natl Coll Technol, Dept Mat Sci & Chem Engn, Kokuraminami Ku, Shi 5-20-1, Kitakyushu, Fukuoka 8020985, Japan
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2014年 / 70卷
关键词：
single-crystal X-ray study; T= 100 K; mean sigma(C; C) = 0.003 (A)over-circle; R factor = 0.022; wR factor = 0.058; data-to-parameter ratio = 21.7;
D O I：
10.1107/S1600536814013336
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The structure of the title compound, [La( C5H7O2) (3)( H2O) (2)], has been redetermined to modern standards with anisotropic displacement parameters for all non-H atoms and the hydrogen-bonding pattern unambiguously established [for the previous study, see Phillips et al. (1968). Inorg. Chem. 7, 2295-2299]. The La 3(+) ion is coordinated by three O, O0bidentate acetylacetate (acac (-)) ligands and two water molecules, resulting in a fairly regular square-antiprismatic LaO8 coordination geometry, with both aqua ligands part of the same square face. In the crystal, the neutral complex molecules are linked into [110] chains by O-H...O hydrogen
引用
收藏
页码：M258 / +
页数：9
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