AN AM1 STUDY OF THE REACTIONS OF OZONE WITH ETHYLENE AND 2-BUTENE

被引：59
作者：
DEWAR, MJS
HWANG, JC
KUHN, DR
机构：
[1] Chemistry Department, University of Texas, Austin
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1991年 / 113卷 / 03期
关键词：
D O I：
10.1021/ja00003a001
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Detailed AM1 calculations are reported for the reactions of ozone with ethylene and with cis- and trans-2-butene. The results support the Criegee mechanisms and are consistent with the available experimental evidence. Implications concerning the stereochemistry of ozonolysis are discussed.
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页码：735 / 741
页数：7
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